Synthetic and structural studies of mono-acetylide and unsymmetric bis-acetylide complexes based on CoIII-cyclam
نویسندگان
چکیده
منابع مشابه
Cooperative self-assembly of platinum(II) acetylide complexes.
Rod-like platinum(II) acetylide complexes have been demonstrated to form one-dimensional helical supramolecular polymers by the cooperative growth mechanism, leading to supramolecular gels by bundling single fibrils into entangled networks.
متن کاملTerpyridine-platinum(II) acetylide complexes bearing pendent coordination units.
Platinum(II) complexes bearing various alkyne-pyrene, alkyne-4'-terpyridine and alkyne-dibutoxyphenylacetylide-terpyridine units were constructed in a step-by-step procedure based on copper-promoted cross-coupling reactions with preconstructed modules; formation of bis(ligand) complexes of Fe(II) and Zn(II) by binding of the pendent terpyridine units provided heterotrinuclear derivatives, all o...
متن کاملDithia[3.3]paracyclophane-based monometal ruthenium acetylide complexes: synthesis, characterization and substituent effects.
A series of dithia[3.3]metaparacyclophane-based monometal ruthenium acetylide complexes have been synthesized. All of the complexes have been fully characterised by NMR spectrometry, X-ray crystallography and elemental analyses. At the same time, their basic optical properties, such as UV/Vis absorption spectra, and electrochemical properties have been determined. (1)H NMR and X-ray crystal str...
متن کاملpostnatal studies of bats (pipistrellus kuhlii and miniopterus schreibersii) & histomorphology and histochemistry studies of organs and diseases of (neurergus microspilotus and n. kaiseri)
1. to determine whether difference in birth body mass influenced growth performance in pipistrellus kuhlii we studied a total of 12 captive-born neonates. bats were assigned to two body mass groups: light birth body mass (lbw: 0.89 ± 0.05, n=8) and heavy birth body mass (hbw: 1.35 ± 0.08, n=4). heavier body mass at birth was associated with rapid postnatal growth (body mass and forearm length) ...
Radical ion states of platinum acetylide oligomers.
The ion radicals of two series of platinum acetylide oligomers have been subjected to study by electrochemical and pulse radiolysis/transient absorption methods. One series of oligomers, Ptn, has the general structure Ph-C[triple bond]C-[Pt(PBu3)2-C[triple bond]C-(1,4-Ph)-C[triple bond]C-]n-Pt(PBu3)2-C[triple bond]C-Ph (where x=0-4, Ph=phenyl and 1,4-Ph=1,4-phenylene). The second series of olig...
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 2015
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2015.09.001